Pyrazolino [60]fullerenes: synthesis and properties

被引：19

作者：

Langa, Fernando ^{[1
]}

Oswald, Frederic ^{[1
]}

机构：

[1] Univ Castilla La Mancha, Dept Quim Organ, Toledo 45071, Spain

来源：

COMPTES RENDUS CHIMIE | 2006年 / 9卷 / 7-8期

关键词：

fullerenes; electron transfer; electrochemistry; donor-acceptor dyads;

D O I：

10.1016/j.crci.2005.11.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe our contribution to the functionalization of fullerenes by 1,3-dipolar cycloaddition reactions in the preparation of pyrazolino [60]fullerenes. Several advantages that are inherent in the use of nitrile imines, with respect to other procedures for the derivatization Of C-60, will be discussed. Electrochemical and photochemical properties of this new family of fullerene derivatives suggest that they are good candidates for incorporation into new donor-acceptor assemblies.

引用

页码：1058 / 1074

页数：17

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