7.7% Efficient All-Polymer Solar Cells

被引:408
作者
Hwang, Ye-Jin [1 ,2 ]
Courtright, Brett A. E. [1 ,2 ]
Ferreira, Amy S. [3 ,4 ]
Tolbert, Sarah H. [3 ,4 ]
Jenekhe, Samson A. [1 ,2 ]
机构
[1] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA
[2] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[3] Univ Calif Los Angeles, Calif NanoSyst Inst, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[4] Univ Calif Los Angeles, Calif NanoSyst Inst, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
基金
美国国家科学基金会;
关键词
all-polymer solar cells; benzodithiophene-thieno[3; 4-b]thiophene copolymer; blend self-organization; naphthalene diimide copolymers; polymer; polymer blends; CONJUGATED POLYMERS; PHOTOVOLTAIC PROPERTIES; ELECTRON-TRANSPORT; BLEND MORPHOLOGY; ACCEPTOR; DONOR; PERFORMANCE; COPOLYMER; DESIGN; PHOTOCURRENT;
D O I
10.1002/adma.201501604
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By controlling the polymer/polymer blend self-organization rate, all-polymer solar cells composed of a high-mobility, crystalline, naphthalene diimide-selenophene copolymer acceptor and a benzodithiophene-thieno[3,4-b]thiophene copolymer donor are achieved with a record 7.7% power conversion efficiency and a record short-circuit current density (18.8 mA cm-2). © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4578 / 4584
页数:7
相关论文
共 50 条
[1]   Design of New Electron Acceptor Materials for Organic Photovoltaics: Synthesis, Electron Transport, Photophysics, and Photovoltaic Properties of Oligothiophene-Functionalized Naphthalene Diimides [J].
Ahmed, Eilaf ;
Ren, Guoqiang ;
Kim, Felix S. ;
Hollenbeck, Emily C. ;
Jenekhe, Samson A. .
CHEMISTRY OF MATERIALS, 2011, 23 (20) :4563-4577
[2]   Efficient solar cells from layered nanostructures of donor and acceptor conjugated polymers [J].
Alam, MM ;
Jenekhe, SA .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4647-4656
[3]   Nanophase-separated blends of acceptor and donor conjugated polymers.: Efficient electroluminescence from binary polyquinoline/poly(2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene) and polyquinoline/poly(3-octylthiophene) blends [J].
Alam, MM ;
Tonzola, CJ ;
Jenekhe, SA .
MACROMOLECULES, 2003, 36 (17) :6577-6587
[4]   Mobility and fill factor correlation in geminate recombination limited solar cells [J].
Andersson, L. Mattias ;
Mueller, Christian ;
Badada, Bekele H. ;
Zhang, Fengling ;
Wuerful, Uli ;
Inganas, Olle .
JOURNAL OF APPLIED PHYSICS, 2011, 110 (02)
[5]   n-Type Organic Semiconductors in Organic Electronics [J].
Anthony, John E. ;
Facchetti, Antonio ;
Heeney, Martin ;
Marder, Seth R. ;
Zhan, Xiaowei .
ADVANCED MATERIALS, 2010, 22 (34) :3876-3892
[6]   Improvement of open-circuit voltage and photovoltaic properties of 2D-conjugated polymers by alkylthio substitution [J].
Cui, Chaohua ;
Wong, Wai-Yeung ;
Li, Yongfang .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (07) :2276-2284
[7]   All-Polymer Bulk Heterojuction Solar Cells with 4.8% Efficiency Achieved by Solution Processing from a Co-Solvent [J].
Earmme, Taeshik ;
Hwang, Ye-Jin ;
Subramaniyan, Selvam ;
Jenekhe, Samson A. .
ADVANCED MATERIALS, 2014, 26 (35) :6080-+
[8]   All-Polymer Solar Cells with 3.3% Efficiency Based on Naphthalene Diimide-Selenophene Copolymer Acceptor [J].
Earmme, Taeshik ;
Hwang, Ye-Jin ;
Murari, Nishit M. ;
Subramaniyan, Selvam ;
Jenekhe, Samson A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (40) :14960-14963
[9]   Polymer donor-polymer acceptor (all-polymer) solar cells [J].
Facchetti, Antonio .
MATERIALS TODAY, 2013, 16 (04) :123-132
[10]   Influence of polymer-blend morphology on charge transport and photocurrent generation in donor-acceptor polymer blends [J].
Frost, Jarvist M. ;
Cheynis, Fabien ;
Tuladhar, Sachetan M. ;
Nelson, Jenny .
NANO LETTERS, 2006, 6 (08) :1674-1681