Organic Catalysis for Ring-Opening Polymerization

被引：450

作者：

Dove, Andrew P. ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

ACS MACRO LETTERS | 2012年 / 1卷 / 12期

关键词：

N-HETEROCYCLIC CARBENES; ORGANOCATALYTIC LIVING POLYMERIZATION; CYCLIC ESTERS; EPSILON-CAPROLACTONE; ZWITTERIONIC POLYMERIZATION; PHOSPHAZENE BASES; FACILE SYNTHESIS; BETA-LACTONES; LACTIDE; ACIDS;

D O I：

10.1021/mz3005956

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Organic catalysis in ring-opening polymerization (ROP) has become a powerful alternative to more traditional metal-based catalysts. The field has developed to a point at which there are not only excellent low cost and easy to use organocatalysts for day-to-day polymerizations, but the ability to precisely control the synthesis of advanced polymer architectures and ROP monomers that are extremely challenging to polymerize with other catalysts now exists. This viewpoint article will highlight the key advances in organocatalyst design with the aim of encouraging the wider application of organic catalysts in ROP.

引用

页码：1409 / 1412

页数：4

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