Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition

被引:227
作者
Cui, HengBo
Wang, Zheming
Takahashi, Kazuyuki
Okano, Yoshinori
Kobayashi, Hayao [1 ]
Kobayashi, Akiko
机构
[1] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Peking Univ, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
[4] Nihon Univ, Coll Humanities & Sci, Dept Chem, Setagaya Ku, Tokyo 1568550, Japan
关键词
D O I
10.1021/ja0665390
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A porous molecular crystal with guest ethanol molecules, [Mn3(HCOO)6](C2H5OH), was found to be a new type of multifunctional molecular system, which exhibits a ferroelectric transition at 165 K and a ferrimagnetic transition at 8.5 K. [Mn3(HCOO)6](C2H5OH) will give a hint to design multiferroic" molecular materials where ferroelectric and ferromagnetic orders coexist. Copyright © 2006 American Chemical Society."
引用
收藏
页码:15074 / 15075
页数:2
相关论文
共 9 条
  • [1] [Anonymous], PHYS CHEM SOLIDS
  • [2] A route to high surface area, porosity and inclusion of large molecules in crystals
    Chae, HK
    Siberio-Pérez, DY
    Kim, J
    Go, Y
    Eddaoudi, M
    Matzger, AJ
    O'Keeffe, M
    Yaghi, OM
    [J]. NATURE, 2004, 427 (6974) : 523 - 527
  • [3] Dielectric properties of porous molecular crystals that contain polar molecules
    Cui, HB
    Takahashi, K
    Kano, Y
    Kobayashi, H
    Wang, ZM
    Kobayashi, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) : 6508 - 6512
  • [4] Goodenough J. B., 1963, MAGNETISM CHEM BOND
  • [5] Guest-dependent spin crossover in a nanoporous molecular framework material
    Halder, GJ
    Kepert, CJ
    Moubaraki, B
    Murray, KS
    Cashion, JD
    [J]. SCIENCE, 2002, 298 (5599) : 1762 - 1765
  • [6] Jora F., 1962, FERROELECTRIC CRYSTA
  • [7] Methane and carbon dioxide storage in a porous van der Waals crystal
    Sozzani, P
    Bracco, S
    Comotti, A
    Ferretti, L
    Simonutti, R
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (12) : 1816 - 1820
  • [8] Mn3(HCOO)6:: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4 tetrahedron and guest-modulated ordering temperature
    Wang, ZM
    Zhang, B
    Fujiwara, H
    Kobayashi, H
    Kurmoo, M
    [J]. CHEMICAL COMMUNICATIONS, 2004, (04) : 416 - 417
  • [9] Magnetic reversal of the ferroelectric polarization in a multiferroic spinel oxide
    Yamasaki, Y.
    Miyasaka, S.
    Kaneko, Y.
    He, J. -P.
    Arima, T.
    Tokura, Y.
    [J]. PHYSICAL REVIEW LETTERS, 2006, 96 (20)