Methane and carbon dioxide storage in a porous van der Waals crystal

被引：358

作者：

Sozzani, P ^{[1
]}

Bracco, S ^{[1
]}

Comotti, A ^{[1
]}

Ferretti, L ^{[1
]}

Simonutti, R ^{[1
]}

机构：

[1] Univ Milano Bicocca, Dept Mat Sci, I-20125 Milan, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 12期

关键词：

adsorption; gas storage; inclusion compounds; nanostructures; pi interactions;

D O I：

10.1002/anie.200461704

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Molecular gas jars: Methane and carbon dioxide can be stored in open-pore van der Waals crystals of tris-o-phenylenedioxycyclotriphosphazene at low partial pressure, whereas hydrogen, nitrogen, and oxygen are selectively excluded. Gas molecules participate in the supramolecular network of weak interactions and reside in the tight nanochannels in close contact with the surrounding aromatic rings (see picture). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1816 / 1820

页数：5

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