Metal complexes with 'pincer'-type ligands incorporating N-heterocyclic carbene functionalities

被引:590
作者
Pugh, David [1 ]
Danopoulos, Andreas A. [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SOU 1BJ, Hants, England
关键词
carbenes; pincer; tridentate; rigid; crystal structures; transition metals;
D O I
10.1016/j.ccr.2006.08.001
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination and organometallic chemistry of linear, rigid, tridentate ligands, which incorporate at least one N-heterocyclic carbene and other 'classical' donors, is reviewed across the periodic table with emphasis on unique features due to the presence of the N-heterocyclic carbene donor. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:610 / 641
页数:32
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共 100 条
  • [1] Reactions of transition-metal metallocenes with stable carbenes
    Abernethy, CD
    Clyburne, JAC
    Cowley, AH
    Jones, RA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (10) : 2329 - 2330
  • [2] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC PROPERTIES OF COPPER(II) COMPOUNDS CONTAINING NITROGEN SULFUR DONOR LIGANDS - THE CRYSTAL AND MOLECULAR-STRUCTURE OF AQUA[1,7-BIS(N-METHYLBENZIMIDAZOL-2'-YL)-2,6-DITHIAHEPTANE]COPPER(II) PERCHLORATE
    ADDISON, AW
    RAO, TN
    REEDIJK, J
    VANRIJN, J
    VERSCHOOR, GC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (07): : 1349 - 1356
  • [3] Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol)
    Aihara, H
    Matsuo, T
    Kawaguchi, H
    [J]. CHEMICAL COMMUNICATIONS, 2003, (17) : 2204 - 2205
  • [4] Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO
  • [5] 2-6
  • [6] Imidazo[1,5-a]pyridine:: A versatile architecture for stable N-heterocyclic carbenes
    Alcarazo, M
    Roseblade, SJ
    Cowley, AR
    Fernández, R
    Brown, JM
    Lassaletta, JM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) : 3290 - 3291
  • [7] Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes
    Andavan, GTS
    Bauer, EB
    Letko, CS
    Hollis, TK
    Tham, FS
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (24-25) : 5938 - 5947
  • [8] An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2
    Appelhans, LN
    Zuccaccia, D
    Kovacevic, A
    Chianese, AR
    Miecznikowski, JR
    Macchioni, A
    Clot, E
    Eisenstein, O
    Crabtree, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (46) : 16299 - 16311
  • [9] Synthesis and small molecule reactivity of uranium(IV) alkoxide complexes with both bound and pendant N-heterocyclic carbene ligands
    Arnold, PL
    Blake, AL
    Wilson, C
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (20) : 6095 - 6099
  • [10] Di- and trivalent ruthenium complexes of chelating, anionic N-heterocyclic carbenes
    Arnold, PL
    Scarisbrick, AC
    [J]. ORGANOMETALLICS, 2004, 23 (11) : 2519 - 2521