Amphiphilicity of a lignin-carbohydrate complex

被引:17
作者
Uraki, Yasumitsu [1 ]
Usukura, Yuriko [1 ]
Kishimoto, Takao [1 ]
Ubukata, Makoto [1 ]
机构
[1] Hokkaido Univ, Grad Sch Agr, Div Appl Biosci, Kita Ku, Sapporo, Hokkaido 0608589, Japan
关键词
amphiphilicity; dynamic light scattering (DLS); Langmuir-Blodgett (LB) film; lignin-carbohydrate complex (LCC); magnesium 1-anilinonaphtalene-8-sulfonate (ANS); pi-A profile; self-aggregation; sonication; static light scattering (SLC);
D O I
10.1515/HF.2006.111
中图分类号
S7 [林业];
学科分类号
0829 ; 0907 ;
摘要
A lignin-carbohydrate complex (LCC) fraction isolated from the residue of milled wood lignin extraction of birch was found to form self-aggregates in water. The aggregates had relatively strong hydrophobic domains, comparable to the hydrophobicity of 80% ethanol. Dynamic light scattering analysis showed that the aggregates were transformed into small particles by sonication with a number-average diameter of 43.7 +/- 9.6 nm, and were stable in water. The surface pressure (pi)-surface area (A) profile showed that the LCC also formed a monolayer on the water surface. Based on these results, we suggest that the LCC is amphiphilic in nature, despite its insolubility in low-polarity organic solvents.
引用
收藏
页码:659 / 664
页数:6
相关论文
共 28 条
[21]   VISCOMETRIC AND SPECTROSCOPIC STUDIES ON THE SOLUTION BEHAVIOR OF HYDROPHOBICALLY MODIFIED CELLULOSIC POLYMERS [J].
TANAKA, R ;
MEADOWS, J ;
PHILLIPS, GO ;
WILLIAMS, PA .
CARBOHYDRATE POLYMERS, 1990, 12 (04) :443-459
[22]   INTERACTION OF HYDROPHOBICALLY MODIFIED (HYDROXYETHYL)CELLULOSE WITH VARIOUS ADDED SURFACTANTS [J].
TANAKA, R ;
MEADOWS, J ;
WILLIAMS, PA ;
PHILLIPS, GO .
MACROMOLECULES, 1992, 25 (04) :1304-1310
[23]  
Tanaka R., 1972, Mokuzai Gakkaishi (Journal of the Japan Wood Research Society), V18, P403
[24]   Vesicle formation in oleyldimethylamine oxide/sodium oleate mixtures [J].
Tanaka, S ;
Kawasaki, H ;
Suzuki, M ;
Annaka, M ;
Nemoto, N ;
Almgren, M ;
Maeda, H .
COLLOID AND POLYMER SCIENCE, 2004, 282 (10) :1140-1145
[25]   Self-assembly of pulp derivatives as amphiphilic compounds: Preparation of amphiphilic compound from acetic acid pulp and its properties as an inclusion compound [J].
Uraki, Y ;
Hashida, K ;
Sano, Y .
HOLZFORSCHUNG, 1997, 51 (01) :91-97
[26]   Self-assembly of pulp derivatives as amphiphilic compounds: Verification of molecular association and complexation with low and high molecular mass compounds [J].
Uraki, Y ;
Hanzaki, A ;
Hashida, K ;
Sano, Y .
HOLZFORSCHUNG, 2000, 54 (05) :535-540
[27]   LIGNIN CARBOHYDRATE COMPLEX .3. FORMATION OF MICELLES IN THE AQUEOUS-SOLUTION OF ACIDIC LIGNIN CARBOHYDRATE COMPLEX [J].
YAKU, F ;
TSUJI, S ;
KOSHIJIMA, T .
HOLZFORSCHUNG, 1979, 33 (02) :54-59
[28]   Liposome-doped nanocomposites as artificial-cell-based biosensors: Detection of listeriolysin O [J].
Zhao, JX ;
Jedlicka, SS ;
Lannu, JD ;
Bhunia, AK ;
Rickus, JL .
BIOTECHNOLOGY PROGRESS, 2006, 22 (01) :32-37