Electronic transitions and resonance electron scattering measured by electron energy loss spectroscopy of lead phthalocyanine thin film

被引：15

作者：

Salomon, E ^{[1
]}

Papageorgiou, N ^{[1
]}

Ferro, Y ^{[1
]}

Layet, JM ^{[1
]}

机构：

[1] Univ Aix Marseille 1, CNRS, UMR 6633, Lab Phys Interact Ion & Mol, F-13397 Marseille 20, France

来源：

THIN SOLID FILMS | 2004年 / 466卷 / 1-2期

关键词：

lead phthalocyanine; electron energy loss spectroscopy; organic semiconductors; molecular electronics;

D O I：

10.1016/j.tsf.2004.02.024

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have measured the electronic transitions of a lead phthalocyanine thin film by means of optical absorption and reflection electron energy loss spectroscopy in the range from 1 to 20 eV We compare the optical absorption spectrum with the loss spectra and discuss their similarity. We identify the loss structures and we report a new absorption band at 10 eV. In addition we report that the inelastic electron scattering from the lower energy pi-->pi* transition and from the C-H stretching vibrational mode show energy-dependent structure, characteristic of resonance scattering via temporary negative ion states. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：259 / 264

页数：6

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