Synthesis of brookite TiO2 nanoparticles by ambient condition sol process

被引：74

作者：

Lee, BI ^{[1
]}

Wang, XY

Bhave, R

Hu, M

机构：

[1] Clemson Univ, Sch Mat Sci & Engn, Clemson, SC 29634 USA

[2] Oak Ridge Natl Lab, Oak Ridge, TN 37831 USA

来源：

MATERIALS LETTERS | 2006年 / 60卷 / 9-10期

关键词：

brookite; ceramics; nanoparticles; powder technology; titania;

D O I：

10.1016/j.matlet.2005.10.114

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Brookite TiO2 nanoparticles were prepared by ambient condition sol process of hydrolyzing TiCl4 in an acidic alcohol under refluxing. The spherical morphology of the particles was found from the SEM and TEM micrographs. The crystalline nature and the brookite phase were confirmed from the X-ray diffractometry. The mean particle size was found to be in the range of 30 nm. Agglomerate formation was observed and could be predicted from the heat released during the hydrolysis of TiCl4. This work presents a simple/direct method for the preparation of high purity brookite TiO2 nanoparticles. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1179 / 1183

页数：5

共 48 条

[21] Chemical and microstructural properties of TiO2 synthesized by sol-gel procedure
Music, S
Gotic, M
Ivanda, M
Popovic, S
Turkovic, A
Trojko, R
Sekulic, A
Furic, K
[J]. MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1997, 47 (01): : 33 - 40
[22] Mechanism for visible light responses in anodic photocurrents at N-doped TiO2 film electrodes
Nakamura, R
Tanaka, T
Nakato, Y
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (30) : 10617 - 10620
[23] RETRACTED: Preparation of ultrafine crystalline TiO2 powders from aqueous TiCl4 solution by precipitation(Retracted article. See vol. 56, Artn No. 069201, 2017)
Nam, HD
Lee, BH
Kim, SJ
Jung, CH
Lee, JH
Park, S
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 1998, 37 (08): : 4603 - 4608
[24] Preparation of S-doped TiO2 photocatalysts and their photocatalytic activities under visible light
Ohno, T
Akiyoshi, M
Umebayashi, T
Asai, K
Mitsui, T
Matsumura, M
[J]. APPLIED CATALYSIS A-GENERAL, 2004, 265 (01) : 115 - 121
[25] A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS
OREGAN, B
GRATZEL, M
[J]. NATURE, 1991, 353 (6346) : 737 - 740
[26] VECTORIAL ELECTRON INJECTION INTO TRANSPARENT SEMICONDUCTOR MEMBRANES AND ELECTRIC-FIELD EFFECTS ON THE DYNAMICS OF LIGHT-INDUCED CHARGE SEPARATION
OREGAN, B
MOSER, J
ANDERSON, M
GRATZEL, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (24) : 8720 - 8726
[27] Understanding of homogeneous spontaneous precipitation for monodispersed TiO2 ultrafine powders with rutile phase around room temperature
Park, SD
Cho, YH
Kim, WW
Kim, SJ
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1999, 146 (01) : 230 - 238
[28] Synthesis of brookite TiO2 nanoparticles by thermolysis of TiCl4 in strongly acidic aqueous media
Pottier, A
Chanéac, C
Tronc, E
Mazerolles, L
Jolivet, JP
[J]. JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (04) : 1116 - 1121
[29] RESEMEYER T, 1993, ROCKS MINER, V68, P327
[30] Daylight photocatalysis by carbon-modified titanium dioxide
Sakthivel, S
Kisch, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (40) : 4908 - 4911

← 1 2 3 4 5 →