Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries

被引:390
作者
Doe, Robert E. [1 ]
Han, Ruoban [1 ]
Hwang, Jaehee [1 ]
Gmitter, Andrew J. [1 ]
Shterenberg, Ivgeni [2 ]
Yoo, Hyun Deog [2 ]
Pour, Nir [2 ]
Aurbach, Doron [2 ]
机构
[1] Pell Technol, Cambridge, MA 02139 USA
[2] Bar Ilan Univ, Dept Chem, IL-92100 Ramat Gan, Israel
关键词
STRUCTURAL-ANALYSIS; COMPLEXES;
D O I
10.1039/c3cc47896c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein the first inorganic magnesium salt solution capable of highly reversible magnesium electrodeposition is presented. Synthesized by acid-base reaction of MgCl2 and Lewis acidic compounds such as AlCl3, this salt class demonstrates upwards of 99% Coulombic efficiency, deposition overpotential of <200 mV, and anodic stability of 3.1 V.
引用
收藏
页码:243 / 245
页数:3
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