LATE TRANSITION METAL-OXO COMPOUNDS AND OPEN-FRAMEWORK MATERIALS THAT CATALYZE AEROBIC OXIDATIONS

被引：18

作者：

Cao, Rui ^{[1
]}

Han, Jong Woo ^{[1
]}

Anderson, Travis M. ^{[1
]}

Hillesheim, Daniel A. ^{[1
]}

Hardcastle, Kenneth I. ^{[1
]}

Slonkina, Elena ^{[2
]}

Hedman, Britt B. B. ^{[2
]}

Hodgson, Keith O. ^{[2
]}

Kirk, Martin L. ^{[3
]}

Musaev, Djamaladdin G. ^{[4
]}

Morokuma, Keiji ^{[4
]}

Geletii, Yurii V. ^{[1
]}

Hill, Craig L. ^{[1
]}

机构：

[1] Emory Univ, Dept Chem, Atlanta, GA 30322 USA

[2] Stanford Univ, SLAC, Stanford Synchrotron Radiat Lab, Stanford, CA 94309 USA

[3] Univ New Mexico, Dept Chem & Chem Biol, Albuquerque, NM 87131 USA

[4] Emory Univ, Cherry L Emerson Ctr, Atlanta, GA 30322 USA

来源：

ADVANCES IN INORGANIC CHEMISTRY, VOL 60 | 2008年 / 60卷

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/S0898-8838(08)00006-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

After decades of speculation and attempted synthesis, terminal metal-oxo compounds of the late transition metal elements have been prepared. Terminal Pt-, Pd-, and Au-oxo complexes have been made using polytungstate ligands that share geometrical and electronic structural features and chemical properties (acid-base and others) in common with the metal oxides used as supports for these metals in myriad industrial catalytic processes.Up to 17 techniques, many addressed in this review, have been used to confirm the Late Transition Metal Oxo (LTMO) species exist and arise from direct reaction with O2. Metal organic frameworks (MOFs) that catalyze the oxidation of organic substrates using O2/air as the terminal oxidant are also described. Molecules or materials with this capability could be used to make fabrics, surfaces, nanostructures and other materials that catalytically purify and decontaminate using only ambient air. © 2008 Elsevier Inc. All rights reserved.

引用

页码：245 / 272

页数：28

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[81] Highly reactive catalysts for aerobic thioether oxidation - The Fe-substituted polyoxometalate/hydrogen dinitrate system [J].