A furan-containing diiron azadithiolate hexacarbonyl complex with unusual lower catalytic proton reduction potential

被引：42

作者：

Jiang, Shi

Liu, Jianhui

Sun, Licheng

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

[2] Royal Inst Technol, KTH Chem, S-10044 Stockholm, Sweden

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 03期

关键词：

hydrogenases; furan; diiron azadithiolate; proton reduction potential;

D O I：

10.1016/j.inoche.2005.11.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new biomimetic model of the active site of Fe-only hydrogenase [{(mu-SCH2)(2)N(2-C4H3O)} Fe-2(CO)(6)] (6) was synthesized and characterized by IR, H-1, C-13 NMR spectroscopy. The butterfly based core structure was also confirmed by X-ray diffraction. The electrochemistry data indicated that the reductive potential at -1.13 V versus Fc/Fc(+) by HClO4 is the lowest of that reported. (C) 2005 Elsevier B.V. All rights reserved.

引用

页码：290 / 292

页数：3

共 24 条

[1] Bioinorganic chemistry - Hydrogenase sophistication [J].