Low-activation solid-state syntheses by reducing transport lengths to atomic scales as demonstrated by case studies on AgNO3 and AgO

被引：50

作者：

Fischer, D ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 14期

关键词：

D O I：

10.1021/ja017845a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have studied solid-state reactions of educt mixtures of elements in an atomic dispersion. The reduced transport distances allow for extremely low activated reactions. This has been demonstrated by case studies on AgNO3 and AgO, which form and crystallize from the atoms below room temperature. Copyright © 2002 American Chemical Society.

引用

页码：3488 / 3489

页数：2

共 23 条

[1]

[Anonymous], ANGEW CHEM

[2]

Corey E. J., 1991, ANGEW CHEM, V103, P469

[3] THE LOGIC OF CHEMICAL SYNTHESIS - MULTISTEP SYNTHESIS OF COMPLEX CARBOGENIC MOLECULES [J].

COREY, EJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :455-465

[4] SOLID-STATE CHEMISTRY - A REDISCOVERED CHEMICAL FRONTIER [J].

DISALVO, FJ .

SCIENCE, 1990, 247 (4943) :649-655

[5]

FISCHER D, 2002, IN PRESS ANGEW CHEM

[6]

FISTER L, 1994, ADV SYN R S, V2, P155

[7] UBER DIE KATALYSE DER REAKTIONEN DER PEROXYDISCHWEFELSAURE .1. KATALYSIERTE ZERSETZUNG DER PEROXYDISCHWEFELSAURE [J].

GALIBA, H ;

CSANYI, LJ ;

SZABO, ZG .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1956, 287 (03) :152-168

[8]

HOLLEMANN AF, 1976, LEHRBUCH ANORGANISCH, P309

[9] Synthesis of superlattices of intercalated transition metal dichalcogenides [J].

Hughes, TA ;

Kevan, SD ;

Cox, DE ;

Johnson, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (37) :8910-8915

[10] A NEW METHOD FOR SYNTHESIS OF MONOCLINIC SILVER(I,III)OXIDE (AGO), SINGLE-CRYSTAL PRODUCTION AND X-RAY STRUCTURE-ANALYSIS [J].

JANSEN, M ;

FISCHER, P .

JOURNAL OF THE LESS-COMMON METALS, 1988, 137 (1-2) :123-131

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