Low-activation solid-state syntheses by reducing transport lengths to atomic scales as demonstrated by case studies on AgNO3 and AgO

被引:50
作者
Fischer, D [1 ]
Jansen, M [1 ]
机构
[1] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
关键词
D O I
10.1021/ja017845a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have studied solid-state reactions of educt mixtures of elements in an atomic dispersion. The reduced transport distances allow for extremely low activated reactions. This has been demonstrated by case studies on AgNO3 and AgO, which form and crystallize from the atoms below room temperature. Copyright © 2002 American Chemical Society.
引用
收藏
页码:3488 / 3489
页数:2
相关论文
共 23 条
[21]   Determination, prediction, and understanding of structures, using the energy landscapes of chemical systems -: Part III [J].
Schön, JC ;
Jansen, M .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2001, 216 (07) :361-383
[22]   Determination, prediction, and understanding of structures, using the energy landscapes of chemical systems -: Part I [J].
Schön, JC ;
Jansen, M .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2001, 216 (06) :307-325
[23]   HIGHER OXIDATION STATES OF SILVER .1. REACTION OF OZONE WITH SIMPLE SILVER SALTS [J].
SELBIN, J ;
USATEGUI, M .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1961, 20 (1-2) :91-99