Hydrogen production from highly corroding Mg-based materials elaborated by ball milling

被引:82
作者
Grosjean, MH [1 ]
Zidoune, M [1 ]
Roué, L [1 ]
机构
[1] INRS Energie, Mat & Telecommun, Varennes, PQ J3X 1S2, Canada
关键词
hydrogen storage materials; magnesium; high-energy ball milling; hydrolysis reaction; corrosion;
D O I
10.1016/j.jallcom.2004.10.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is universally known that the reaction between magnesium or magnesium hydride and water produces hydrogen. However, this reaction stops rapidly due to the formation of a passive Mg(OH)(2) layer onto the reactive material. In this paper, we present an investigation of the hydrogen production by hydrolysis of Mg-based materials elaborated by high-energy ball milling. The best performance is obtained with a Mg-10 at.% Ni composite material milled for 30 min, which leads to a conversion yield of 100% after I h of hydrolysis in neutral aqueous solution containing chloride ions. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:712 / 715
页数:4
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