A mixed-linker porphyrin framework with CdI2-type topology

被引：41

作者：

Choi, Eun-Young ^{[1
]}

Barron, Paul M. ^{[1
]}

Novotney, Richard W. ^{[1
]}

Hu, Chunhua ^{[2
]}

Kwon, Young-Uk ^{[3
]}

Choe, Wonyoung ^{[1
]}

机构：

[1] Univ Nebraska, Dept Chem, Lincoln, NE 68588 USA

[2] Univ Nebraska, Nebraska Ctr Mat & Nanosci, Lincoln, NE 68588 USA

[3] Sungkyunkwan Univ, Dept Chem, Sch Chem Mat Sci BK21, Suwon 440176, South Korea

来源：

CRYSTENGCOMM | 2008年 / 10卷 / 07期

关键词：

D O I：

10.1039/b720035h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel metal-organic framework, [(Co(cis-ZnDCPP)(bpy)]. 4DMF.H2O(cis-ZnDCPP = zinc 5,10-di(4-carboxyphenyl)-15,20-diphenylporphyrin; bpy = 4,4'-bipyridine; DMF = dimethyl formamide), has been synthesized from the solvothermal reaction and exhibits unique CdI2 layers constructed from paddle-wheel buiding units, Co-2(COO)(4), cis-ZnDCPP, and bipyridine linker.

引用

收藏

页码：824 / 826

页数：3

相关论文

共 31 条

[1] Porphyrin "flying-saucers": Solid state and solution structure of a novel pentameric array of axially-ligated canted porphyrins [J].

Alessio, E ;

Geremia, S ;

Mestroni, S ;

Srnova, I ;

Slouf, M ;

Gianferrara, T ;

Prodi, A .

INORGANIC CHEMISTRY, 1999, 38 (10) :2527-+

[2]

[Anonymous], PORPHYRIN HDB

[3] Coordination networks of C3ν and C2ν phenylacetylene nitriles and silver(I) salts:: Interplay of ligand symmetry and molecular dipole moments in the solid state [J].

Choe, W ;

Kiang, YH ;

Xu, ZT ;

Lee, S .

CHEMISTRY OF MATERIALS, 1999, 11 (07) :1776-1783

[4] Benzene-templated hydrothermal synthesis of metal-organic frameworks with selective sorption properties [J].

Choi, EY ;

Park, K ;

Yang, CM ;

Kim, H ;

Son, JH ;

Lee, SW ;

Lee, YH ;

Min, D ;

Kwon, YU .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (21) :5535-5540

[5]

CHOI EY, 2007, ANGEW CHEM INT UNPUB

[6]

CHOU JH, 2000, PORPHYRIN HDB, V6, P43

[7] Reversible single-crystal-to-single-crystal guest exchange in a 3-D coordination network based on a zinc porphyrin [J].

Deiters, E ;

Bulach, V ;

Hosseini, MW .

CHEMICAL COMMUNICATIONS, 2005, (31) :3906-3908

[8] Single crystalline commensurate metallic assemblages of π-slabs and Cdl2-type layers:: Synthesis and properties of β-(EDT-TTF-l2)2[Pb5/6□1/6l2]3 and β-(EDT-TTF-l2)2[Pb2/3+xAg1/3-2x□xl2]3, x=0.05 [J].

Devic, T ;

Evain, M ;

Moëlo, Y ;

Canadell, E ;

Auban-Senzier, P ;

Fourmigué, M ;

Batail, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (11) :3295-3301

[9]

Diskin-Posner Y, 2000, ANGEW CHEM INT EDIT, V39, P1288, DOI 10.1002/(SICI)1521-3773(20000403)39:7<1288::AID-ANIE1288>3.0.CO

[10]

2-Y

← 1 2 3 4 →