New polymers by metallocene catalysis

被引:692
作者
Kaminsky, W
机构
[1] Inst. Tech. and Macromolec. Chem., University of Hamburg, 20146 Hamburg
关键词
D O I
10.1002/macp.1996.021971201
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Work in the field of application of metallocene-based catalysis in olefin, diolefin and styrene polymerization has become a research topic of growing interest in recent years. A great number of symmetric and chiral zirconocenes have been synthesized, that give tailored polymers of totally different structures. Single Site catalysts have the capability of permitting the user to control polymer tacticity, molecular weight and molecular weight distribution more efficiently. Beside the homopolymers of polyethylene and poly(propylene), new kinds of copolymers and elastomers can be synthesized.
引用
收藏
页码:3907 / 3945
页数:39
相关论文
共 107 条
[1]   HALOGEN-FREE SOLUBLE ZIEGLER CATALYSTS FOR POLYMERIZATION OF ETHYLENE - CONTROL OF MOLECULAR-WEIGHT BY CHOICE OF TEMPERATURE [J].
ANDRESEN, A ;
CORDES, HG ;
HERWIG, J ;
KAMINSKY, W ;
MERCK, A ;
MOTTWEILER, R ;
PEIN, J ;
SINN, H ;
VOLLMER, HJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1976, 15 (10) :630-632
[2]  
ANDRESEN A, 1976, ANGEW CHEM, V88, P688
[3]   POLYMERIZATION WITH METALLOCENE CATALYSTS - HYDROOLIGOMERIZATION AND NMR INVESTIGATIONS CONCERNING THE MICROSTRUCTURE OF POLY(CYCLOPENTENES) [J].
ARNDT, M ;
KAMINSKY, W .
MACROMOLECULAR SYMPOSIA, 1995, 95 :167-183
[4]  
ARNDT M, 1996, CATALYSIS S FRIEDRIC
[5]   A NEW UNDERSTANDING OF THE CO-CATALYTIC ACTIVITY OF ALUMOXANES - THE OPENING OF A BLACK-BOX [J].
BARREN, AR .
MACROMOLECULAR SYMPOSIA, 1995, 97 :15-25
[6]   Cationic Group 4 metallocene complexes and their role in polymerisation catalysis: The chemistry of well defined Ziegler catalysts [J].
Bochmann, M .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (03) :255-270
[7]   BIS-(CYCLOPENTADIENYL)-TITANIUM DICHLORIDE-ALKYLALUMINUM COMPLEXES AS CATALYSTS FOR THE POLYMERIZATION OF ETHYLENE [J].
BRESLOW, DS ;
NEWBURG, NR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (18) :5072-5073
[8]  
Brintzinger H. H., 1995, ANGEW CHEM, V107, P1255
[9]   STRUCTURE-ACTIVITY AND STRUCTURE-SELECTIVITY CORRELATIONS IN METALLOCENE-BASED CATALYSTS FOR ALPHA-OLEFIN POLYMERIZATION [J].
BURGER, P ;
HORTMANN, K ;
BRINTZINGER, HH .
MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1993, 66 :127-139
[10]   Propene polymerization promoted by C-2-symmetric metallocene catalysts: From atactic to isotactic polypropene in consequence of an isotope effect [J].
Busico, V ;
Caporaso, L ;
Cipullo, R ;
Landriani, L ;
Angelini, G ;
Margonelli, A ;
Segre, AL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (08) :2105-2106