Trojanoside H:: a cycloartane-type glycoside from the aerial parts of Astragalus trojanus

被引:51
作者
Bedir, E
Çalis, I [1 ]
Aquino, R
Piacente, S
Pizza, C
机构
[1] Hacettepe Univ, Fac Pharm, Dept Pharmacognosy, TR-06100 Ankara, Turkey
[2] Univ Salerno, Dipartimento Sci Farmaceut, I-84084 Salerno, Italy
关键词
Astragalus trojanus; Leguminosae; cycloartane type glycoside; trojanoside H; isoflavone; Maackiain;
D O I
10.1016/S0031-9422(99)00035-7
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A novel cycloartane-type glycoside was isolated from the aerial parts of Astragalus trojanus along with the known glycosides astragaloside II, astragaloside IV, astragaloside VII, brachyoside B, brachyoside C and the pterocarpan derivative maackiain. The structure of 1 was determined by spectral methods (1-D and 2-D NMR, and FABMS) and established as 3-O-beta-[alpha-L-arabinopyranosyl(1 --> 2)beta-D-xylopyranosyl]-6-O-beta-D-glucopyranosyl-20(R),24(S)-epoxy-3 beta,6 alpha,16 beta,25-tetrahydroxycycloartane. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1017 / 1020
页数:4
相关论文
共 15 条
[11]  
KITAGAWA I, 1983, CHEM PHARM BULL, V31, P716
[12]   INVERSE-DETECTED 2-DIMENSIONAL NMR METHODS - APPLICATIONS IN NATURAL-PRODUCTS CHEMISTRY [J].
MARTIN, GE ;
CROUCH, RC .
JOURNAL OF NATURAL PRODUCTS, 1991, 54 (01) :1-70
[13]   Constituents of Ardisia japonica and their in vitro anti-HIV activity [J].
Piacente, S ;
Pizza, C ;
deTommasi, N ;
Mahmood, N .
JOURNAL OF NATURAL PRODUCTS, 1996, 59 (06) :565-569
[14]  
WU LJ, 1985, CHEM PHARM BULL, V33, P3231
[15]  
[No title captured]