Nanoporous solid acid catalyst for the Diels-Alder reaction of 1,3-dienes with acrylates

被引：11

作者：

Onaka, M ^{[1
]}

Hashimoto, N ^{[1
]}

Yamasaki, R ^{[1
]}

Kitabata, Y ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Grad Sch Arts & Sci, Meguro Ku, Tokyo 1538902, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 02期

关键词：

D O I：

10.1246/cl.2002.166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nanoporous aluminosilicate, Al-HMS with a high aluminum content, strong acidity, and nanoporosity was found to catalyze the Diels-Alder reaction of 1,3-dienes with methacrylate and acrylate, and turned out to be a green alternative to homogeneous acid catalysts.

引用

页码：166 / 167

页数：2

共 14 条

[1] FACTORS INFLUENCING THE K10 MONTMORILLONITE-CATALYZED DIELS-ALDER REACTION BETWEEN METHYL ACRYLATE AND CYCLOPENTADIENE [J].

CATIVIELA, C ;

FRAILE, JM ;

GARCIA, JI ;

MAYORAL, JA ;

FIGUERAS, F ;

DEMENORVAL, LC ;

ALONSO, PJ .

JOURNAL OF CATALYSIS, 1992, 137 (02) :394-407

[2] Diels-Alder reactions in ionic liquids - A safe recyclable alternative to lithium perchlorate-diethyl ether mixtures [J].

Earle, MJ ;

McCormac, PB ;

Seddon, KR .

GREEN CHEMISTRY, 1999, 1 (01) :23-25

[3]

GIRUERE RJ, 1986, TETRAHEDRON LETT, V27, P4945

[4] DRAMATIC RATE ACCELERATIONS OF DIELS-ALDER REACTIONS IN 5-M LITHIUM PERCHLORATE DIETHYL-ETHER - THE CANTHARIDIN PROBLEM REEXAMINED [J].

GRIECO, PA ;

NUNES, JJ ;

GAUL, MD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4595-4596

[5] LANTHANIDE TRIFLUOROMETHANESULFONATES AS REUSABLE CATALYSTS - MICHAEL AND DIELS-ALDER REACTIONS [J].

KOBAYASHI, S ;

HACHIYA, I ;

TAKAHORI, T ;

ARAKI, M ;

ISHITANI, H .

TETRAHEDRON LETTERS, 1992, 33 (45) :6815-6818

[6]

NARAYANA MYVS, 1991, SYNTHETIC COMMUN, V21, P783

[7] Catalysis by solid acid: Selective Diels-Alder reactions are promoted by mesoporous aluminosilicate with zinc ions and nanometer honeycomb openings [J].

Onaka, M ;

Yamasaki, R .

CHEMISTRY LETTERS, 1998, (03) :259-260

[8] THE CYCLOADDITION REACTIONS OF UNSATURATED ESTERS WITH CYCLOPENTADIENE ON GAMMA-ALUMINA [J].

PAGNI, RM ;

KABALKA, GW ;

HONDROGIANNIS, G ;

BAINS, S ;

ANOSIKE, P ;

KURT, R .

TETRAHEDRON, 1993, 49 (31) :6743-6756

[9] Textural mesoporosity and the catalytic activity of mesoporous molecular sieves with wormhole framework structures [J].

Pauly, TR ;

Liu, Y ;

Pinnavaia, TJ ;

Billinge, SJL ;

Rieker, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (38) :8835-8842

[10] Sonochemical synthesis of norbornane derivatives using allene cyclopentadiene Diels-Alder cycloaddition [J].

Raj, CP ;

Dhas, NA ;

Cherkinski, M ;

Gedanken, A ;

Braverman, S .

TETRAHEDRON LETTERS, 1998, 39 (30) :5413-5416

← 1 2 →