Unexpected formation of the isopropylamine complex [2,3,4,5-Ph4(η4-C4CO)](CO)2Ru(H2NCHMe2) in the attempted synthesis of an isopropyl alcohol complex

被引：21

作者：

Casey, CP

Bikzhanova, GA

Bäckvall, JE

Johansson, L

Park, J

Kim, YH

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

[2] Stockholm Univ, Arrhenius Lab, Dept Organ Chem, SE-10691 Stockholm, Sweden

[3] Pohang Univ Sci & Technol, Dept Chem, Ctr Integrated Mol Syst, Pohang 790784, South Korea

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 09期

关键词：

D O I：

10.1021/om020097t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [2,3,4,5-Ph-4(eta(4)-C4CO)]Ru(CO)(3) (5a) with Na2CO3 in aqueous acetone followed by low-temperature treatment with NH4Cl was reported to give the material A, which was formulated as the isopropyl alcohol complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(HOCHMe2) (3a). Reinvestigation of this reaction indicates that A is instead the isopropylamine complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(H2NCHMe2) (4a). The formation of 4a is proposed to occur by formation of the imine of acetone followed by reduction of the imine by the (hydroxycyclopentadienyl)ruthenium hydride [2,3,4,5-Ph-4(eta(5)-C4COH)]Ru(CO)(2)H (2a) formed in the reaction of 5a with Na2CO3 in aqueous acetone and subsequent acidification with aqueous NH4Cl.

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页码：1955 / 1959

页数：5

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