Catalysis by metal nanoparticles embedded on metal-organic frameworks

被引：954

作者：

Dhakshinamoorthy, Amarajothi

Garcia, Hermenegildo ^{[1
]}

机构：

[1] Univ Politecn Valencia, Inst Univ Tecnol Quim CSIC UPV, Valencia 46022, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 15期

关键词：

POROUS COORDINATION POLYMERS; SUPPORTED GOLD NANOPARTICLES; EFFICIENT HETEROGENEOUS CATALYSTS; AEROBIC ALCOHOL OXIDATION; CHEMICAL-VAPOR-DEPOSITION; CROSS-COUPLING REACTIONS; HIGHLY-ACTIVE CATALYSTS; SILVER NANOPARTICLES; CO OXIDATION; ATMOSPHERIC-PRESSURE;

D O I：

10.1039/c2cs35047e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present review describes the use of metal-organic frameworks (MOFs) as porous matrices to embed metal nanoparticles (MNPs) and occasionally metal oxide clusters, which are subsequently used as heterogeneous catalysts. The review is organized according to the embedded metal including Pd, Au, Ru, Cu, Pt, Ni and Ag. Emphasis is also given in the various methodologies reported for the formation of the NPs and the characterization techniques. The reactions described with this type of solid catalysts include condensation, hydrogenations, carbon-carbon coupling, alcohol oxidations and methanol synthesis among others. Remaining issues in this field have also been indicated.

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页码：5262 / 5284

页数：23

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