Hydrogen complexes in epitaxial BaTiO3 thin films

被引:18
作者
Yi, GC [1 ]
Block, BA [1 ]
Wessels, BW [1 ]
机构
[1] NORTHWESTERN UNIV,MAT RES CTR,DEPT MAT SCI & ENGN,EVANSTON,IL 60208
关键词
D O I
10.1063/1.119529
中图分类号
O59 [应用物理学];
学科分类号
摘要
Hydrogen complexes in epitaxial BaTiO3 thin films are investigated using Fourier transform infrared spectroscopy. Both undoped and Er-doped layers were grown using low-pressure metalorganic chemical vapor deposition. From the infrared spectra of the undoped and Er-doped films grown at 750-800 degrees C, infrared absorption was observed at 3486 cm(-1). The absorption peak is attributed to a vibrational mode of O-H in BaTiO3. Moreover, the Er-doped layers showed additional absorption peaks at 2905 and 2964 cm(-1). The peaks are ascribed to the vibrational modes of C-H complexes in the Er-doped layers. (C) 1997 American Institute of Physics.
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页码:327 / 329
页数:3
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