A new synthetic route towards a Ru(III) substituted heteropolytungstate anion

被引：21

作者：

Besson, Claire ^{[1
]}

Chen, Su-Wen ^{[1
]}

Villanneau, Richard ^{[1
]}

Izzet, Guillaume ^{[1
]}

Proust, Anna ^{[1
]}

机构：

[1] Univ Paris 06, Inst Parisien Chim Mol, Equipe Polyoxometallates, UPMC,UMR 7201, F-75252 Paris 05, France

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 10期

关键词：

Ruthenium; Polyoxometalates; EPR spectroscopy; XANES; Microwave activation; STRUCTURAL-CHARACTERIZATION; POLYOXOMETALATE COMPLEXES; HYDROTHERMAL SYNTHESIS; RUTHENIUM; OXIDATION; CATALYST; REACTIVITY; CHEMISTRY; CLUSTERS; BEHAVIOR;

D O I：

10.1016/j.inoche.2009.08.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Microwave irradiation of a mixture of K-7[PW11O39]center dot 14H(2)O and [Ru(dmf)(6)](CF3SO3)(3) allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)](4-) anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for Ru-III-incorporating heteropolytungstates. (C) 2009 Elsevier B.V. All rights reserved.

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页码：1042 / 1044

页数：3

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