Hydrothermal synthesis of ruthenium-substituted heteropolyanion, [SiW11O39Ru(III)(H2O)]5- as a water soluble oxidation catalyst

被引：37

作者：

Higashijima, M ^{[1
]}

机构：

[1] Mitsubishi Chem Corp, Yokohama Res Ctr, Chem Lab, Yokohama, Kanagawa 2278502, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 10期

关键词：

D O I：

10.1246/cl.1999.1093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tris (acetylacetonate)ruthenium, Ru(acac)(3), successfully reacts with the lacunary heteropolyoxometalate, K-8[SiW11O39] under hydrothermal conditions (6 MPa nitrogen at 200 degrees C), to give the mono-substituted heteropolyanion, [SiW11O39Ru(III)(H2O)](5-). The heteropolyanion shows notable activity on the air oxidation of alkylaromatics at 200 degrees C in water as solvent.

引用

页码：1093 / 1094

页数：2

共 12 条

[1] COORDINATION, ELECTRON-TRANSFER AND CATALYTIC CHEMISTRY OF A RUTHENIUM-SUBSTITUTED HETEROPOLYTUNGSTATE ANION AS REVEALED IN ITS ELECTROCHEMICAL-BEHAVIOR [J].

BART, JC ;

ANSON, FC .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 390 (1-2) :11-19

[2] STUDY OF THE ELECTROCATALYTIC REDUCTION OF NITRITE WITH SILICOTUNGSTIC HETEROPOLYANION [J].

DONG, SJ ;

XI, XD ;

TIAN, M .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1995, 385 (02) :227-233

[3] SYNTHESIS, CHARACTERIZATION AND REACTIVITY OF RUTHENIUM COMPLEXES OF THE LACUNARY KEGGIN POLYOXOANION - [SIW(11)O(39)RUL](N-), L=H2O, NO, N-2 [J].

FILIPEK, K .

INORGANICA CHIMICA ACTA, 1995, 231 (1-2) :237-239

[4] HOMOGENEOUS CATALYSIS BY TRANSITION-METAL OXYGEN ANION CLUSTERS [J].

HILL, CL ;

PROSSERMCCARTHA, CM .

COORDINATION CHEMISTRY REVIEWS, 1995, 143 :407-455

[5] Heteropoly compounds .30. Alkane oxidation with mixed addenda heteropoly catalysts containing Ru(III) and Rh(III) [J].

Matsumoto, Y ;

Asami, M ;

Hashimoto, M ;

Misono, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 114 (1-3) :161-168

[6] ALKENE OXIDATION CATALYZED BY A RUTHENIUM-SUBSTITUTED HETEROPOLYANION, SIRU(L)W11O39 - THE MECHANISM OF THE PERIODATE MEDIATED OXIDATIVE CLEAVAGE [J].

NEUMANN, R ;

ABUGNIM, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (16) :6025-6031

[7] OXIDATION RESISTANT INORGANIC-PORPHYRIN ANALOG POLYOXOMETALATES .3. THE SYNTHESIS AND X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF A NEW HETEROPOLYOXOANION STRUCTURAL TYPE, THE DIRUTHENIUM OXO-BRIDGED BIMETALLIC INORGANIC-PORPHYRIN ANALOG KLI15[O(RUIVCL(ALPHA-2-P2W17O61))2].2KCL.60H2O [J].

RANDALL, WJ ;

WEAKLEY, TJR ;

FINKE, RG .

INORGANIC CHEMISTRY, 1993, 32 (07) :1068-1071

[8] LACUNARY POLYOXOMETALATE ANIONS ARE PI-ACCEPTOR LIGANDS - CHARACTERIZATION OF SOME TUNGSTORUTHENATE(II,III,IV,V) HETEROPOLYANIONS AND THEIR ATOM-TRANSFER REACTIVITY [J].

RONG, CY ;

POPE, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :2932-2938

[9] Electrochemical properties of polyoxometalates as electrocatalysts [J].

Sadakane, M ;

Steckhan, E .

CHEMICAL REVIEWS, 1998, 98 (01) :219-237

[10]

SEDDON EA, 1984, CHEM RUTHENIUM, P156

← 1 2 →