OXIDATION RESISTANT INORGANIC-PORPHYRIN ANALOG POLYOXOMETALATES .3. THE SYNTHESIS AND X-RAY CRYSTALLOGRAPHIC CHARACTERIZATION OF A NEW HETEROPOLYOXOANION STRUCTURAL TYPE, THE DIRUTHENIUM OXO-BRIDGED BIMETALLIC INORGANIC-PORPHYRIN ANALOG KLI15[O(RUIVCL(ALPHA-2-P2W17O61))2].2KCL.60H2O

被引：87

作者：

RANDALL, WJ

WEAKLEY, TJR

FINKE, RG

机构：

[1] UNIV OREGON, DEPT CHEM, EUGENE, OR 97403 USA

[2] LEWIS & CLARK COLL, DEPT CHEM, PORTLAND, OR 97219 USA

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1021/ic00059a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and unequivocal characterization by X-ray crystallography of a Ru-containing polyoxanion ''bimetallic inorganic-porphyrin analog'' is reported, [O{Ru(IV)Cl(alpha2-P2W17O61)}2]16-. The structural results reveal a new polyoxoanion Structural type, a Ru-O-Ru oxo-bridged-dimer anion that is structurally analogous to bimetallic metalloporphyrins containing mu-oxo M-O-M bridge. Such new types of polyoxoanions are of current interest as oxidation-resistant oxidation catalysts and for their Possible multielectron redox reactivity.

引用

收藏

页码：1068 / 1071

页数：4

相关论文

共 102 条

[1] A NEW FUNDAMENTAL TYPE OF INORGANIC COMPLEX - HYBRID BETWEEN HETEROPOLY AND CONVENTIONAL COORDINATION COMPLEXES - POSSIBILITIES FOR GEOMETRICAL ISOMERISMS IN 11-HETEROPOLY, 12-HETEROPOLY, 17-HETEROPOLY, AND 18-HETEROPOLY DERIVATIVES [J].

BAKER, LCW ;

FIGGIS, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (12) :3794-&

[2]

BAKER LCW, 1973, 15 PLEN LECT INT C C

[3] THE STEREOSPECIFIC EPOXIDATION OF OLEFINS CATALYZED BY RUTHENIUM [J].

BALAVOINE, G ;

ESKENAZI, C ;

MEUNIER, F ;

RIVIERE, H .

TETRAHEDRON LETTERS, 1984, 25 (30) :3187-3190

[4] SYNTHESIS AND PROPERTIES OF SUBSTITUTED RUTHENIUM AQUA COMPLEXES [J].

BERNHARD, P ;

LEHMANN, H ;

LUDI, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (23) :1216-1217

[5] A MODIFIED SYNTHESIS OF RUTHENIUM(II) HEXAAQUA SALTS [J].

BERNHARD, P ;

BINER, M ;

LUDI, A .

POLYHEDRON, 1990, 9 (08) :1095-1097

[6] ELECTRON-TRANSFER REACTIONS INVOLVING THE AQUORUTHENIUM(II)-AQUORUTHENIUM(III) COUPLE [J].

BOTTCHER, W ;

BROWN, GM ;

SUTIN, N .

INORGANIC CHEMISTRY, 1979, 18 (06) :1447-1451

[7] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[8] THE DETERMINATION OF THE FORMULAS OF AQUEOUS RUTHENIUM(III) SPECIES BY MEANS OF ION-EXCHANGE RESIN - RU+3, RUCL+2 AND RUCL2+ [J].

CADY, HH ;

CONNICK, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (11) :2646-2652

[9] SYNTHESIS, STRUCTURE, AND ELECTROCHEMISTRY OF DIHALOBIS(ALPHA-BENZIL OXIMATO)RUTHENIUM(III) [J].

CHAKRAVARTY, AR ;

CHAKRAVORTY, A .

INORGANIC CHEMISTRY, 1981, 20 (01) :275-278

[10] RUTHENIUM OXO COMPLEXES OF MACROCYCLIC TERTIARY-AMINES - SYNTHESIS, ELECTROCHEMISTRY, AND REACTIVITIES OF RUTHENIUM OXO COMPLEXES OF MESO-2,3,7,11,12-PENTAMETHYL-3,7,11,17-TETRA-AZABICYCLO[11.3.1]HEPTADECA-1(17),13,15-TRIENE (L1), AND X-RAY CRYSTAL-STRUCTURE OF TRANS-[RUIVL1(O)(NCO)]CLO4 [J].

CHE, CM ;

TANG, WT ;

LEE, WO ;

WONG, WT ;

LAI, TF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (10) :2011-2016

← 1 2 3 4 5 6 7 8 9 10 →