Planar air breathing PEMFC with self-humidifying MEA and open cathode geometry design for portable applications

被引:85
作者
Bussayajarn, Narissara [1 ]
Ming, Han [2 ]
Hoong, Kwan Kian [2 ]
Stephen, Wan Yee Ming [1 ]
Hwa, Chan Siew [3 ]
机构
[1] Singapore Inst Mfg Technol, Singapore 638075, Singapore
[2] Temasek Polytech, Clean Energy Ctr, Singapore 529757, Singapore
[3] Nanyang Technol Univ, Singapore 639798, Singapore
关键词
Air breathing PEMFC; Self-humidifying MEA; Open cathode design; Purge valve; Dead-end mode; Water removal; PERFORMANCE; STACK; ANODE;
D O I
10.1016/j.ijhydene.2009.07.077
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, planar air breathing PEMFCs without the need for endplates are proposed for low power portable applications. PEMFCs with 3 different cathode designs (parallel slit, circular open and oblique slit) with the same opening ratio and employing self-humidifying MEAs were investigated. Performance and stability tests were conducted in hydrogen dead-end operation under both self-breathing and forced convection condition. It was found that rib geometry and hydraulic diameter have significant impact on oxygen transportation. it was concluded that circular opening design yields the best performance and highest limiting current. This is because this design provides the shortest rib distance and smallest hydraulic diameter. However, fuel cell instability was observed under self-breathing and forced convection condition. This is due to the water accumulation that could not be removed by natural-evaporation at the opening cathode. Overall, our proposed air breathing PEMFC achieves a specific power of 150Wkg(-1) and a power density of 347 mW cm(-3). (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:7761 / 7767
页数:7
相关论文
共 28 条
[21]   Polymer electrolyte fuel cell stack research and development (Reprinted from Int J Hydrogen Energy, vol 33, pg 1941-96, 2008) [J].
Squadrito, G. ;
Barbera, O. ;
Giacoppo, G. ;
Urbani, F. ;
Passalacqua, E. .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (16) :7108-7113
[22]   Effect of cathode separator structure on performance characteristics of free-breathing PEMFCs [J].
Tabe, Yutaka ;
Park, Sang-Kyun ;
Kikuta, Kazushige ;
Chikahisa, Takemi ;
Hishinuma, Yukio .
JOURNAL OF POWER SOURCES, 2006, 162 (01) :58-65
[23]  
UN HJ, 2007, J HYDROGEN ENERGY, V32, P4459
[24]  
WANG Y, 2005, J HYDROGEN ENERGY, V30, P1351
[25]   The influence of the mass transfer on the geometric design of SOFC stacks [J].
Winkler, W .
JOURNAL OF POWER SOURCES, 2000, 86 (1-2) :449-454
[26]   A preliminary study of a six-cell stack with dead-end anode and open-slits cathode [J].
Yang, Tao ;
Shi, Pengfei .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (11) :2795-2801
[27]   Three-dimensional analysis for effect of channel configuration on the performance of a small air-breathing proton exchange membrane fuel cell (PEMFC) [J].
Ying, W ;
Yang, TH ;
Lee, WY ;
Ke, J ;
Kim, CS .
JOURNAL OF POWER SOURCES, 2005, 145 (02) :572-581
[28]  
ZIEGLER C, 2005, P COMSOL MULT US C F