A syn selective dihydroxylation of cyclic allylic trichloroacetamides using catalytic osmium tetroxide

被引：27

作者：

Blades, K

Donohoe, TJ

Winter, JJG

Stemp, G

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[2] SmithKline Beecham Pharmaceut, Harlow CM19 5AW, Essex, England

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/S0040-4039(00)00714-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A range of cyclic allylic trichloroacetamides has been synthesised. Dihydroxylation utilising catalytic osmium tetroxide and quinuclidine-N-oxide monohydrate as the re-oxidant in dichloromethane yields diols with good levels of syn selectivity. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：4701 / 4704

页数：4

共 14 条

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