Interstitial accommodation of C60 in a surface-supported supramolecular network

被引:29
作者
Nishiyama, Fumitaka
Yokoyama, Takashi
Kamikado, Toshiya
Yokoyama, Shiyoshi
Mashiko, Shinro
Sakaguchi, Koichi
Kikuchi, Koichi
机构
[1] Yokohama City Univ, Dept Nanosci & Technol, Kanazawa Ku, Yokohama, Kanagawa, Japan
[2] Kansai Adv Res Ctr, Natl Inst Informat & Commun Technol, Nishi Ku, Kobe, Hyogo 6512401, Japan
[3] Tokyo Metropolitan Univ, Dept Chem, Tokyo 1920397, Japan
关键词
D O I
10.1002/adma.200601364
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fullerene molecules have been accommodated in a supramolecular network formed by carboxyphenyl-substituted porphyrin molecules on a Au(111) surface. The adsorption of C-60 leads to the opening of linear arrays of nanopores in the supramolecular network (see figure). These flexible porous supramolecular networks can selectively accommodate certain molecules and thus may have potential applications in molecular recognition and selective catalysis.
引用
收藏
页码:117 / +
页数:5
相关论文
共 17 条
[1]   Engineering atomic and molecular nanostructures at surfaces [J].
Barth, JV ;
Costantini, G ;
Kern, K .
NATURE, 2005, 437 (7059) :671-679
[2]   Two-dimensional self-assembly of supramolecular clusters and chains [J].
Böhringer, M ;
Morgenstern, K ;
Schneider, WD ;
Berndt, R ;
Mauri, F ;
De Vita, A ;
Car, R .
PHYSICAL REVIEW LETTERS, 1999, 83 (02) :324-327
[3]   STM study of terephthalic acid self-assembly on Au(III): Hydrogen-bonded sheets on an inhomogeneous substrate [J].
Clair, S ;
Pons, S ;
Seitsonen, AP ;
Brune, H ;
Kern, K ;
Barth, JV .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (38) :14585-14590
[4]  
Lehn J-M., 1995, Supramolecular Chemistry: Concepts and Prospectives, DOI 10.1002/3527607439
[5]   Real-time single-molecule imaging of the formation and dynamics of coordination compounds [J].
Lin, N ;
Dmitriev, A ;
Weckesser, J ;
Barth, JV ;
Kern, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (24) :4779-4783
[6]   Conformational changes of single molecules induced by scanning tunneling microscopy manipulation: A route to molecular switching [J].
Moresco, F ;
Meyer, G ;
Rieder, KH ;
Tang, H ;
Gourdon, A ;
Joachim, C .
PHYSICAL REVIEW LETTERS, 2001, 86 (04) :672-675
[7]   Layer-by-layer growth of porphyrin supramolecular thin films [J].
Nishiyama, Fumitaka ;
Yokoyama, Takashi ;
Kamikado, Toshiya ;
Yokoyama, Shiyoshi ;
Mashiko, Shinro .
APPLIED PHYSICS LETTERS, 2006, 88 (25)
[8]   Configurations of a calix[8]arene and a C60/calix[8]arene complex on a Au(111) surface [J].
Pan, GB ;
Liu, JM ;
Zhang, HM ;
Wan, LJ ;
Zheng, QY ;
Bai, CL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (24) :2747-2751
[9]   A two-dimensional porphyrin-based porous network featuring communicating cavities for the templated complexation of fullerenes [J].
Spillmann, H ;
Kiebele, A ;
Stöhr, M ;
Jung, TA ;
Bonifazi, D ;
Cheng, FY ;
Diederich, F .
ADVANCED MATERIALS, 2006, 18 (03) :275-+
[10]   Steering molecular organization and host-guest interactions using two-dimensional nanoporous coordination systems [J].
Stepanow, S ;
Lingenfelder, M ;
Dmitriev, A ;
Spillmann, H ;
Delvigne, E ;
Lin, N ;
Deng, XB ;
Cai, CZ ;
Barth, JV ;
Kern, K .
NATURE MATERIALS, 2004, 3 (04) :229-233