Heteroarylation of anthraquinone-triflate by Suzuki cross-coupling

被引：34

作者：

Coudret, C

Mazenc, V

机构：

[1] Grp. Electronique Moléculaire, CEMES, 31055 Toulouse

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(97)01155-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reactivity of the 4-pyridylboronate 5a for PdCl2(dppf)-catalysed cross-coupling reaction with an anthraquinone triflate is presented, and compared with its 2-thienyl- and phenylboronic analogues. Best results have been obtained on a small scale with anhydrous K3PO4 using an O-2-scavenger or under rigorously anaerobic conditions. (C) 1997 Published by Elsevier Science Ltd.

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页码：5293 / 5296

页数：4

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