Stable Adducts of a Dimeric Magnesium(I) Compound

被引：213

作者：

Green, Shaun P. ^{[1
,2
]}

Jones, Cameron ^{[1
]}

Stasch, Andreas ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Cardiff Univ, Sch Chem, Cardiff CF10 3AT, S Glam, Wales

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 47期

关键词：

low oxidation states; magnesium; metal hydrides; metal-metal bonding; structure elucidation;

D O I：

10.1002/anie.200803960

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long Mg-Mg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low-energy processes. The structures of the magnesium(I) adducts are compared with those of related magnesium(II) hydride complexes (see picture; Mg pink, N blue, O red, H green). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9079 / 9083

页数：5

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