Recent progress in endohedral dimetallofullerenes

被引：36

作者：

Nagase, S ^{[1
]}

Kobayashi, K ^{[1
]}

Akasaka, T ^{[1
]}

机构：

[1] NIIGATA UNIV, GRAD SCH SCI & TECHNOL, NIIGATA 95021, JAPAN

来源：

JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM | 1997年 / 398卷

关键词：

endohedral dimetallofullerenes; cage structures; metal positions and motion; electronic states; reactivities;

D O I：

10.1016/S0166-1280(96)05001-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Encapsulation of two metal atoms inside hollow fullerene cages is of current interest since new spherical cage molecules are Formed. The isolation and purification of endohedral dimetallofullerenes such as La-2@C-80 ana Sc-2@C-84 in macroscopic quantities have made it possible to investigate the structures, properties and chemical reactivities. Recent progress in the theoretical and experimental studies is summarized. (C) 1997 Elsevier Science B.V.

引用

页码：221 / 227

页数：7

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