Synthesis and X-ray crystal structures of mononuclear complexes of 1,3-bis(8-quinolyloxy)propane

被引:17
作者
Al-Mandhary, MRA
Steel, PJ [1 ]
机构
[1] Univ Canterbury, Dept Chem, Christchurch 1, New Zealand
[2] Sultan Qaboos Univ, Coll Sci, Al Khoud 123, Oman
关键词
D O I
10.1071/CH02128
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparations and X-ray crystal structures of the first transition metal complexes of 1,3-bis(8-quinolyloxy)propane (2) are described. The ligand acts as a trans-chelating N,N'-bidentate ligand in the three-coordinate silver(I) nitrate complex (3) and four-coordinate copper(II) chloride complex (4), but as an N,O,O',N'-tetradentate ligand in the octahedral nickel(II) chloride complex (5).
引用
收藏
页码:705 / 708
页数:4
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