Iododecarboxylation of α-carboxylate, α-cinnamoyl ketene cyclic dithioacetals

被引：33

作者：

Wang, M

Xu, XX

Liu, Q ^{[1
]}

Xiong, L

Yang, B

Gao, LX

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Acad Sinica, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2002年 / 32卷 / 22期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1081/SCC-120014773

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The iododecarboxylation reaction of alpha-carboxylate, alpha-cinnamoyl ketene cyclic dithioacetals 2 was successfully performed with iodine as halogenation reagent and in water insensitive media. This reaction provides a mild and efficient method for the preparation of alpha-iodo, alpha-cinnamoyl ketene cyclic dithioacetals 3 which are important kinds of potential new intermediates to be valued.

引用

页码：3437 / 3443

页数：7

共 18 条

[1]

BARTLETT PA, 1984, ASYMMETRIC SYNTHESIS, P3

[2] STEREOCONTROLLED CYCLOFUNCTIONALIZATIONS OF DOUBLE-BONDS THROUGH HETEROCYCLIC INTERMEDIATES [J].