A synthetic approach to the pseudopterosins

被引：54

作者：

Gill, S

Kocienski, P

Kohler, A

Pontiroli, A

Qun, L

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

[2] NE NORMAL UNIV,DEPT CHEM,CHANGCHUN 130024,PEOPLES R CHINA

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 15期

关键词：

D O I：

10.1039/cc9960001743

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three Lewis acid catalysed reactions used in a synthesis of the tricyclic core of the marine anti-inflammatory pseudopterosins are reported; the reductive cleavage of an oxirane with inversion, the cyclisation of an alpha-hydroxy ketenedithioacetal to an arene, and a stereoselective annulation using an allylic sulfone as the electrophile.

引用

页码：1743 / 1744

页数：2

共 21 条

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