Highly efficient Grignard-type imine additions via C-H activation in water and under solvent-free conditions

被引：353

作者：

Li, CJ ^{[1
]}

Wei, CM ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b108851n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly effective Cu-Ru catalyzed addition of terminal alkynes to imines via C-H activation has been achieved in water or under solvent-free conditions.

引用

页码：268 / 269

页数：2

共 23 条

[11]

LAI YH, 1981, SYNTHESIS-STUTTGART, P585

[12]

Li C. -J., 1997, ORGANIC REACTIONS AQ

[13]

LI CJ, 2002, IN PRESS GREEN CHEM, V4

[14]

LUBINEAU A, 1994, SYNTHESIS-STUTTGART, P741

[15]

LUBINEAU A, 1998, ORGANIC SYNTHESIS WA

[16] COPPER-CATALYZED REACTION OF TERMINAL ALKYNES WITH NITRONES - SELECTIVE SYNTHESIS OF 1-AZA-1-BUTEN-3-YNE AND 2-AZETIDINONE DERIVATIVES [J].

MIURA, M ;

ENNA, M ;

OKURO, K ;

NOMURA, M .

JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (16) :4999-5004

[17] Ruthenium-catalyzed reactions for organic synthesis [J].

Naota, T ;

Takaya, H ;

Murahashi, SI .

CHEMICAL REVIEWS, 1998, 98 (07) :2599-2660

[18]

Normat H., 1960, ADV ORG CHEM, V2, P1

[19]

SHELDON RA, 1994, CHEMTECH, V24, P38

[20] THE ATOM ECONOMY - A SEARCH FOR SYNTHETIC EFFICIENCY [J].

TROST, BM .

SCIENCE, 1991, 254 (5037) :1471-1477

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