Solution process for the synthesis of the "high-pressure'' phase CoMoO4 and X-ray single crystal resolution

被引：39

作者：

Livage, C ^{[1
]}

Hynaux, A ^{[1
]}

Marrot, J ^{[1
]}

Nogues, M ^{[1
]}

Férey, G ^{[1
]}

机构：

[1] Univ Versailles, Inst Lavoisier Franklin, CNRS, UMR 8637 8638, F-78035 Versailles, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2002年 / 12卷 / 05期

关键词：

D O I：

10.1039/b110760g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A mild solution method was developed to grow single crystals of CoMoO4-II. The structure was solved by single crystal X-ray diffraction [P2/c, a = 4.6598(7) Angstrom, b = 5.6862(9) Angstrom, c = 4.9159(7) Angstrom, beta = 90.521(3)degrees, V = 130.25(3) Angstrom(3)] from 349 unique reflections [I greater than or equal to 2sigma(I)], R-1 = 0.0270 and wR(2) = 0.066. CoMoO4-II was characterised by scanning electron microscopy and its magnetic properties investigated.

引用

页码：1423 / 1425

页数：3