A Versatile, Ultralight, Nitrogen-Doped Graphene Framework

被引:681
作者
Zhao, Yang [1 ]
Hu, Chuangang [1 ]
Hu, Yue [1 ]
Cheng, Huhu [1 ]
Shi, Gaoquan [2 ]
Qu, Liangti [1 ]
机构
[1] Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ, Sch Chem, Beijing 100081, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
adsorption; capacitors; graphene; oxygen reduction reaction; ultralight materials; METAL-FREE ELECTROCATALYSTS; REDUCED GRAPHENE; OXIDE; HYDROGELS; AEROGELS;
D O I
10.1002/anie.201206554
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene lite: A density of (2.1±0.3) mg cm -3, the lowest to date for a graphene framework architecture, is achieved by preparing an ultralight, N-doped, 3D graphene framework (see photo of a block of the material balancing on a dandelion). Its adsorption capacity for oils and organic solvents is much higher than that of the best carbonaceous sorbents, and it is a promising electrode material for supercapacitors (484 F g -1) and as a metal-free catalyst for the oxygen reduction reaction. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:11371 / 11375
页数:5
相关论文
共 50 条
[1]  
[Anonymous], 2010, ANGEW CHEMIE, DOI DOI 10.1002/ANGE.201000270
[2]  
Bi H. C., 2012, ADV FUNCT MATER, DOI [10.1002/adfm.201200888, DOI 10.1002/ADFM.201200888
[3]  
]
[4]   Self-Assembly and Embedding of Nanoparticles by In Situ Reduced Graphene for Preparation of a 3D Graphene/Nanoparticle Aerogel [J].
Chen, Wufeng ;
Li, Sirong ;
Chen, Chunhua ;
Yan, Lifeng .
ADVANCED MATERIALS, 2011, 23 (47) :5679-+
[5]  
Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/NMAT3001, 10.1038/nmat3001]
[6]   Macroscopic Multifunctional Graphene-Based Hydrogels and Aerogels by a Metal Ion Induced Self-Assembly Process [J].
Cong, Huai-Ping ;
Ren, Xiao-Chen ;
Wang, Ping ;
Yu, Shu-Hong .
ACS NANO, 2012, 6 (03) :2693-2703
[7]   Facile Fabrication of Light, Flexible and Multifunctional Graphene Fibers [J].
Dong, Zelin ;
Jiang, Changcheng ;
Cheng, Huhu ;
Zhao, Yang ;
Shi, Gaoquan ;
Jiang, Lan ;
Qu, Liangti .
ADVANCED MATERIALS, 2012, 24 (14) :1856-1861
[8]   High oxygen-reduction activity and durability of nitrogen-doped graphene [J].
Geng, Dongsheng ;
Chen, Ying ;
Chen, Yougui ;
Li, Yongliang ;
Li, Ruying ;
Sun, Xueliang ;
Ye, Siyu ;
Knights, Shanna .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (03) :760-764
[9]   Nitrogen-Doped Carbon Nanotube Arrays with High Electrocatalytic Activity for Oxygen Reduction [J].
Gong, Kuanping ;
Du, Feng ;
Xia, Zhenhai ;
Durstock, Michael ;
Dai, Liming .
SCIENCE, 2009, 323 (5915) :760-764
[10]   Carbon Nanotube Sponges [J].
Gui, Xuchun ;
Wei, Jinquan ;
Wang, Kunlin ;
Cao, Anyuan ;
Zhu, Hongwei ;
Jia, Yi ;
Shu, Qinke ;
Wu, Dehai .
ADVANCED MATERIALS, 2010, 22 (05) :617-+