A Versatile, Ultralight, Nitrogen-Doped Graphene Framework

被引:681
作者
Zhao, Yang [1 ]
Hu, Chuangang [1 ]
Hu, Yue [1 ]
Cheng, Huhu [1 ]
Shi, Gaoquan [2 ]
Qu, Liangti [1 ]
机构
[1] Beijing Inst Technol, Key Lab Cluster Sci, Minist Educ, Sch Chem, Beijing 100081, Peoples R China
[2] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
adsorption; capacitors; graphene; oxygen reduction reaction; ultralight materials; METAL-FREE ELECTROCATALYSTS; REDUCED GRAPHENE; OXIDE; HYDROGELS; AEROGELS;
D O I
10.1002/anie.201206554
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene lite: A density of (2.1±0.3) mg cm -3, the lowest to date for a graphene framework architecture, is achieved by preparing an ultralight, N-doped, 3D graphene framework (see photo of a block of the material balancing on a dandelion). Its adsorption capacity for oils and organic solvents is much higher than that of the best carbonaceous sorbents, and it is a promising electrode material for supercapacitors (484 F g -1) and as a metal-free catalyst for the oxygen reduction reaction. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:11371 / 11375
页数:5
相关论文
共 50 条
[41]   Three-Dimensional Nitrogen and Boron Co-doped Graphene for High-Performance All-Solid-State Supercapacitors [J].
Wu, Zhong-Shuai ;
Winter, Andreas ;
Chen, Long ;
Sun, Yi ;
Turchanin, Andrey ;
Feng, Xinliang ;
Muellen, Klaus .
ADVANCED MATERIALS, 2012, 24 (37) :5130-5135
[42]   3D Nitrogen-Doped Graphene Aerogel-Supported Fe3O4 Nanoparticles as Efficient Eletrocatalysts for the Oxygen Reduction Reaction [J].
Wu, Zhong-Shuai ;
Yang, Shubin ;
Sun, Yi ;
Parvez, Khaled ;
Feng, Xinliang ;
Muellen, Klaus .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (22) :9082-9085
[43]  
Xia JL, 2009, NAT NANOTECHNOL, V4, P505, DOI [10.1038/NNANO.2009.177, 10.1038/nnano.2009.177]
[44]   Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process [J].
Xu, Yuxi ;
Sheng, Kaixuan ;
Li, Chun ;
Shi, Gaoquan .
ACS NANO, 2010, 4 (07) :4324-4330
[45]   Carbon Materials for Chemical Capacitive Energy Storage [J].
Zhai, Yunpu ;
Dou, Yuqian ;
Zhao, Dongyuan ;
Fulvio, Pasquale F. ;
Mayes, Richard T. ;
Dai, Sheng .
ADVANCED MATERIALS, 2011, 23 (42) :4828-4850
[46]   Preparation of Highly Conductive Graphene Hydrogels for Fabricating Supercapacitors with High Rate Capability [J].
Zhang, Li ;
Shi, Gaoquan .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (34) :17206-17212
[47]   Carbon-based materials as supercapacitor electrodes [J].
Zhang, Li Li ;
Zhao, X. S. .
CHEMICAL SOCIETY REVIEWS, 2009, 38 (09) :2520-2531
[48]   Strong, transparent, multifunctional, carbon nanotube sheets [J].
Zhang, M ;
Fang, SL ;
Zakhidov, AA ;
Lee, SB ;
Aliev, AE ;
Williams, CD ;
Atkinson, KR ;
Baughman, RH .
SCIENCE, 2005, 309 (5738) :1215-1219
[49]   Nanoporous Graphitic-C3N4@Carbon Metal-Free Electrocatalysts for Highly Efficient Oxygen Reduction [J].
Zheng, Yao ;
Jiao, Yan ;
Chen, Jun ;
Liu, Jian ;
Liang, Ji ;
Du, Aijun ;
Zhang, Weimin ;
Zhu, Zhonghua ;
Smith, Sean C. ;
Jaroniec, Mietek ;
Lu, Gao Qing ;
Qiao, Shi Zhang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20116-20119
[50]   Graphene and Graphene Oxide: Synthesis, Properties, and Applications [J].
Zhu, Yanwu ;
Murali, Shanthi ;
Cai, Weiwei ;
Li, Xuesong ;
Suk, Ji Won ;
Potts, Jeffrey R. ;
Ruoff, Rodney S. .
ADVANCED MATERIALS, 2010, 22 (35) :3906-3924