The crystal structures of [NMe(4)][(Me(2)AsO(2)){MoO(O-2)(2)}(2)], [NMe4][(Ph(2)PO(2)){MoO(O-2)(2)}(2)], [NBu(4)(n)][(Ph(2)PO(2)){WO(O-2)(2)}(2)] and [NH4][(Ph(2)PO(2)){MoO(O-2)(2)(H2O)}] and their use as catalytic oxidants

被引：54

作者：

Gresley, NM ^{[1
]}

Griffith, WP ^{[1
]}

Parkin, BC ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] UNIV LONDON IMPERIAL COLL SCI & TECHNOL,DEPT CHEM,INORGAN & CHEM CRYSTALLOG RES LABS,LONDON SW7 2AY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 10期

关键词：

D O I：

10.1039/dt9960002039

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new heteropolyperoxometalate compounds [NMe(4)][(Me(2)AsO(2)){MoO(O-2)(2)}(2)]1, [NMe(4)][(Ph(2)PO(2)){MoO(O-2)(2)}(2)]2, [NBu(4)(n)][(Ph(2)PO(2)){WO(O-2)(2)}(2)]3 and [NH4][(Ph(2)PO(2)){MoO(O-2)(2)(H2O)}]4 have been isolated and their crystal structures determined. Compounds 1-3 are dinuclear, whilst compound 4 is mononuclear; in all four structures the metal centre(s) have essentially identical pentagonal-bipyramidal co-ordination geometries with a weak axial ligand trans to an oxo group. The utility of 3 as a catalyst for the oxidation of alkenes, alcohols and tertiary amines with hydrogen peroxide as cooxidant has been studied.

引用

页码：2039 / 2045

页数：7

共 22 条

[11] HYDROGEN-PEROXIDE OXIDATION CATALYZED BY HETEROPOLY ACIDS COMBINED WITH CETYLPYRIDINIUM CHLORIDE - EPOXIDATION OF OLEFINS AND ALLYLIC ALCOHOLS, KETONIZATION OF ALCOHOLS AND DIOLS, AND OXIDATIVE CLEAVAGE OF 1,2-DIOLS AND OLEFINS [J].