Lithium storage properties of ball milled Ni-57 mass% Sn alloy

被引:17
作者
Ahn, JH
Kim, YJ
Wang, GX
Lindsay, M
Liu, HK
Dou, SX
机构
[1] Andong Natl Univ, Dept Mat Engn, Andong 760749, Gyungbuk, South Korea
[2] Korea Inst Machinery & Mat, Chang Won 640010, Gyungnam, South Korea
[3] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
关键词
nanocrystalline alloys; lithium-ion batteries; Sn-Ni anode materials; mechanical alloying;
D O I
10.2320/matertrans.43.63
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ni-57 mass%Sn alloy has been examined as a new anode material for Li-ion batteries. Li ions can reversibly intercalate and de-intercalate in this alloy. Ball milled nanocrystalline and subsequently annealed microcrystalline Ni-57 mass%Sn alloy showed very high initial discharge capacity. The cell capacity decayed rapidly after the first discharge. The capacity of the ball milled Ni-57 mass%Sn alloy faded continuously on cycling, while the annealed alloy exhibited good cyclic properties. Therefore, Ni-57 mass%Sn alloy is an attractive intercalation host for Li.
引用
收藏
页码:63 / 66
页数:4
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