Vibrational energy transfer in molecular oxygen collisions

被引:67
作者
Coletti, C
Billing, GD [1 ]
机构
[1] Univ Copenhagen, HC Orsted Inst, Dept Chem, DK-2100 Copenhagen O, Denmark
[2] Univ G DAnnunzio, Fac Farm, I-66100 Chieti, Italy
关键词
D O I
10.1016/S0009-2614(02)00279-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Rate coefficients for the relaxation of vibrational excited oxygen molecules, including both vibration-to-vibration (V-V) and vibration-to-translation (V-T) energy exchange, have been calculated using a semiclassical method and a new potential energy surface for a large interval of initial vibrational quantum numbers (1 less than or equal to v less than or equal to 29) in the temperature range between 50 and 1000 K. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:14 / 22
页数:9
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