New polyelectrolyte architectures

被引:54
作者
Bohrisch, J
Eisenbach, CD
Jaeger, W [1 ]
Mori, H
Müller, AHE
Rehahn, M
Schaller, C
Traser, S
Wittmeyer, P
机构
[1] Fraunhofer Inst Angew Polymer Forsch, D-14476 Golm, Germany
[2] Forschungsinst Pigmente & Lacke eV, D-70569 Stuttgart, Germany
[3] Univ Stuttgart, D-70569 Stuttgart, Germany
[4] Univ Bayreuth, Bayreuther Zentrum Kolloide & Grenzflachen, D-95440 Bayreuth, Germany
[5] Tech Univ Darmstadt, Inst Makromol Chem, D-64287 Darmstadt, Germany
来源
POLYELECTROLYTES WITH DEFINED MOLECULAR ARCHITECTURE I | 2004年 / 165卷
关键词
polyelectrolytes; polycarbobetaines; block copolymers; graft copolymers; reactive precursors;
D O I
10.1007/b11266
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
This chapter reviews recent advances in the synthesis of polyelectrolytes. New results are presented for linear polymers with stiff and flexible backbones and with star-shaped and randomly branched structures. Block and graft copolymers containing both charged ionic and hydrophobic monomer units are also discussed. Homo- and block copolymers of carbobetaines complete the variation of molecular architecture. Synthetic approaches mainly use anionic, controlled radical, and macromonomer polymerization techniques, and the Suzuki reaction, to synthesize reactive precursors which are subsequently transformed into the final products. Results from physicochemical characterization of the new polymers are also mentioned.
引用
收藏
页码:1 / 41
页数:41
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