Synthesis of nanocrystalline Y2O3/Pr3+ from heterometallic alkoxide via sol-gel process

被引:12
作者
Daniele, S [1 ]
Hubert-Pfalzgraf, LG [1 ]
机构
[1] Univ Lyon 1, IRC, F-69626 Villeurbanne, France
关键词
Y2O3/Pr phosphor; nanosized powder; sol-gel process; heterometallic alkoxide;
D O I
10.1016/j.matlet.2003.12.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Y2O3/Pr-3divided by nanoparticulate powder has been prepared through a one-step hydrolytic sol-gel process using an yttrium praseodymium heterometallic alkoxide. The powder was characterized by TGA/TDA, XRD, TEM, XPS and photoluminescent experiments, which showed that a homogeneous and a highly crystalline material was obtained by calcination as low as 500 degreesC. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1989 / 1992
页数:4
相关论文
共 15 条
[1]   Synthesis and luminescent properties of sub-5-nm lanthanide oxides nanoparticles [J].
Bazzi, R ;
Flores-Gonzalez, MA ;
Louis, C ;
Lebbou, K ;
Dujardin, C ;
Brenier, A ;
Zhang, W ;
Tillement, O ;
Bernstein, E ;
Perriat, P .
JOURNAL OF LUMINESCENCE, 2003, 102 :445-450
[2]  
Blasse G., 1994, LUMINESCENT MAT, P26
[3]   OPTICAL COATINGS PREPARED FROM COLLOIDAL MEDIA [J].
FLOCH, HG ;
PRIOTTON, JJ ;
THOMAS, IM .
THIN SOLID FILMS, 1989, 175 :173-178
[4]   Synthesis and characterization of nanocrystalline yttrium oxide prepared with tetraalkylammonium hydroxides [J].
Fokema, MD ;
Chiu, E ;
Ying, JY .
LANGMUIR, 2000, 16 (07) :3154-3159
[5]   Size dependent efficiency in Tb doped Y2O3 nanocrystalline phosphor [J].
Goldburt, ET ;
Kulkarni, B ;
Bhargava, RN ;
Taylor, J ;
Libera, M .
JOURNAL OF LUMINESCENCE, 1997, 72-4 :190-192
[6]   Luminescence properties of Y2O3 single crystals doped with Pr3+ or Tm3+ and codoped with Yb3+, Tb3+ or Ho3+ ions [J].
Guyot, Y ;
Moncorge, R ;
Merkle, LD ;
Pinto, A ;
McIntosh, B ;
Verdun, H .
OPTICAL MATERIALS, 1996, 5 (1-2) :127-136
[7]   Some trends in the design of homo- and heterometallic molecular precursors of high-tech oxides [J].
Hubert-Pfalzgraf, LG .
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (01) :102-120
[8]   Praseodymium alkoxide chemistry: Synthesis and molecular structure of [Pr-4(mu(4)-O)(2)(mu(3)eta(2)-OR)(2)(mu,eta(2)-OR)(4)(mu,eta(l)-OR)(OR)(OPMe(3))](2) (R=C(2)H(4)OMe) and [Y4Pr(mu(5)-O)(mu(3)-OR)(4)(mu-OR)(4)(OR)(5)] (R=Pr-i) [J].
HubertPfalzgraf, LG ;
Daniele, S ;
Bennaceur, A ;
Daran, JC ;
Vaissermann, J .
POLYHEDRON, 1997, 16 (07) :1223-1234
[9]   OPTICAL-SPECTRA, ENERGY-LEVELS, AND CRYSTAL-FIELD ANALYSIS OF TRIPOSITIVE RARE-EARTH IONS IN Y2O3 .2. NON-KRAMERS IONS IN C2 SITES [J].
LEAVITT, RP ;
GRUBER, JB ;
CHANG, NC ;
MORRISON, CA .
JOURNAL OF CHEMICAL PHYSICS, 1982, 76 (10) :4775-4788
[10]   SOL-GEL CHEMISTRY OF TRANSITION-METAL OXIDES [J].
LIVAGE, J ;
HENRY, M ;
SANCHEZ, C .
PROGRESS IN SOLID STATE CHEMISTRY, 1988, 18 (04) :259-341