Dihydroxybenzoquinone and chloranilic acid derivatives of rare earth metals

被引：81

作者：

Abrahams, BF ^{[1
]}

Coleiro, J ^{[1
]}

Ha, K ^{[1
]}

Hoskins, BF ^{[1
]}

Orchard, SD ^{[1
]}

Robson, R ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 08期

关键词：

D O I：

10.1039/b109296k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structures of lanthanide complexes involving the dianions of dihydroxybenzoquinone (H(2)dhbq) or chloranilic acid (H(2)can) are presented. The complexes, Ln(2)dhbq3.24H(2)O (Ln = Y, La, Ce, Gd, Yb and Lu) are 2-D coordination polymers with metal centres linked by dhbq(2-) ligands. Each of these species contain a Ln(2)(H2O)(18) pentagonal dodecahedral cage. Despite the variation in the radii of lanthanide ions this series is isostructural. In contrast, the hydrated structures of Ln(2)can(3) (Ln = Sc, Y, La, Pr, Nd, Gd, Tb, Yb and Lu) show considerable structural variation. The crystal structures of the diamond-like networks Ycan(2)(-) and Thcan(2) are also presented.

引用

页码：1586 / 1594

页数：9

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