Unprecedented use of silver(I) N-heterocyclic carbene complexes for the catalytic preparation of 1,2-bis(boronate) esters

被引:132
作者
Ramírez, J
Corberán, R
Sanaú, M
Peris, E
Fernandez, E
机构
[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona, Spain
[2] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12080, Spain
[3] Univ Valencia, Dept Quim Inorgan, E-46100 Burjassot, Spain
关键词
D O I
10.1039/b503239c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Catalytic diboration of internal and terminal alkenes with Ag( I) N-heterocyclic carbene complexes leads to 1,2-bis(boronate) esters as single intermediates, that can be oxidised towards the corresponding diols.
引用
收藏
页码:3056 / 3058
页数:3
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