High pressure breakdown of antigorite to spinifex-textured olivine and orthopyroxene, SE Spain

The prograde, high pressure, transition from antigorite serpentinite to enstatite-olivine rock occurs along a tectonically undisturbed profile at Cerro del Almirez, SE Spain. The reactant assemblage is antigorite + olivine with tremolite rimming precursor diopside. The product assemblage of tremolite + chlorite + enstatite + olivine has a spinifex-like texture with arborescent or radiating olivine elongated parallel to [001] and with radially grown enstatite. Product enstatite is very poor in Al2O3. Due to numerous oriented submicroscopic inclusions of chromian magnetite, product olivine has a brownish pleochroism and a bulk chromium content similar to precursor antigorite. Titanian clinohumite with a fluorine content of 0.45-0.50 wt% persisted beyond the breakdown of antigorite. The partitioning of iron and magnesium amongst the silicate phases is almost identical to that at lower pressures. Average K-d values Mn/Mg and Ni/Mg are 0.17 and 0.70 for antigorite-olivine pairs and 1.83 and 0.22 for orthopyroxene-olivine pairs, respectively. These data are useful in discriminating generations of olivine grown on each other. From the field data a phase diagram topology for a portion of the system CaO-MgO-SiO2-H2O is derived. This topology forms the basis for extrapolations into inaccessible P-T regions.