Semiclassical dynamics in the coherent control of nonadiabatic ICN photodissociation

被引：22

作者：

Batista, VS ^{[1
]}

Brumer, P

机构：

[1] Univ Toronto, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada

[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[3] Univ Toronto, Photon Res Ontario, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2001年 / 105卷 / 12期

关键词：

D O I：

10.1021/jp0035939

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The utility of a semiclassical initial value representation (SC-IVR) to simulate coherent control is explored. Specifically, bichromatic control of the state specific ICN photodissociation in the (A) over tilde continuum is investigated both quantum mechanically and semiclassically, and the ability of the SC-IVR method to reproduce phases of transition matrix element products is examined. Control over the I(P-2(1/2))II(P-2(3/2)) product ratio is considerable and the resultant semiclassical photofragmentation ratios are in good agreement with full quantum dynamics calculations.

引用

页码：2591 / 2598

页数：8

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