Conducting complexes of TTF and TSF derivatives fused with selenium-containing five-membered rings

被引：9

作者：

Jigami, T ^{[1
]}

Takimiya, K

Aso, Y

Otsubo, T

机构：

[1] Hiroshima Univ, Fac Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Fukuoka 8128581, Japan

来源：

SYNTHETIC METALS | 1999年 / 102卷 / 1-3期

关键词：

electrocrystallization; X-ray diffraction; organic conductors based on radical cation salts;

D O I：

10.1016/S0379-6779(98)00890-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrocrystallization of bis(ethyleneseleno)-tetrathiafulvalene (BES-TTF) and -tetraselenafulvalene (BES-TSF) gave a variety of radical cation salts which had high room-temperature conductivities (60-280 S cm(-1)) and displayed a metal-to-semiconductor (insulator) transition at low temperature. Among them, however, the ClO4- and AsF6- salts of BES-TSF remained highly conducting even at cryogenic temperature. An X-ray crystallographic analysis of (BES-TTF)(2)SbF6, revealed that the complex carries a considerably two-dimensional interactive electronic structure.

引用

页码：1714 / 1715

页数：2

共 12 条

[11] SYNTHESIS, STRUCTURE AND PHYSICAL-PROPERTIES OF CHARGE-TRANSFER COMPLEXES BASED ON BET-TTF AND M(MNT)(2) (M= AU, PT) [J].

TARRES, J ;

MAS, M ;

MOLINS, E ;

VECIANA, J ;

ROVIRA, C ;

MORGADO, J ;

HENRIQUES, RT ;

ALMEIDA, M .

JOURNAL OF MATERIALS CHEMISTRY, 1995, 5 (10) :1653-1658

[12] A NEW FAMILY OF MOLECULAR-METALS BASED OIL BIS(ETHYLENETHIO)TETRATHIAFULVALENE (BET-TTF) AND OCTAHEDRAL COUNTERIONS [J].

TARRES, J ;

SANTALO, N ;

MAS, M ;

MOLINS, E ;

VECIANA, J ;

ROVIRA, C ;

YANG, SL ;

LEE, H ;

COWAN, DO ;

DOUBLET, ML ;

CANADELL, E .

CHEMISTRY OF MATERIALS, 1995, 7 (08) :1558-1567

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