Electrolytic synthesis of ammonia in molten salts under atmospheric pressure

被引:175
作者
Murakami, T [1 ]
Nishikiori, T [1 ]
Nohira, T [1 ]
Ito, Y [1 ]
机构
[1] Kyoto Univ, Grad Sch Energy Sci, Dept Fundamental Energy Sci, Sakyo Ku, Kyoto 6068501, Japan
关键词
D O I
10.1021/ja028891t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ammonia was successfully synthesized by using a new electrochemical reaction with high current efficiency at atmospheric pressure and at lower temperatures than the Haber-Bosch process. In this method, nitride ion (N3-), which is produced by the reduction from nitrogen gas at the cathode, is anodically oxidized and reacts with hydrogen to produce ammonia at the anode. Copyright © 2003 American Chemical Society.
引用
收藏
页码:334 / 335
页数:2
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