De-agglomeration of thorium oxalate - a method for the synthesis of sinteractive thoria

Thorium oxalate was obtained by precipitation in water and in non-aqueous solvents and de-agglomerated by ultrasonication in both aqueous as well as non-aqueous media. Sinteractive thoria (crystallite size 6-20 nm) obtained from the de-agglomerated thorium oxalate was characterised for residual carbon, crystallite size, specific surface area, particle size distribution and bulk density. Microstructure of the precursor and the product was studied using TEM and HRTEM. The morphology of the sintered pellets was studied using SEM. The reactivity of the calcined powders was determined by measuring the density of the sintered compacts. The solvent used for de-agglomeration was found to have significant influence on the microstructure of the powders. Thoria derived through aqueous precipitation route could be sintered to a density of 9.7 Mg m(-3) at 1673 K. It was demonstrated that ultrasonic de-agglomeration could be a useful method for obtaining sinteractive thoria. (C) 2002 Elsevier Science B.V. All rights reserved.